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Thermodynamicsis concerned with transformationsof energy, and the laws of thermodynamics describe the bounds within which these transformations are observed to occur The first law reflects the observation that energy is conserved, but it imposes no restriction on the process direction Yet, all experience indicates the existence of such a restriction, the concise statement of which constitutes the second law The differences between the two forms of energy, heat and work, provide some insight into the second law In an energy balance, both work and heat are included as simple additive terms, implying that one unit of heat, a joule, is equivalent to the same unit of work Although this is true with respect to an energy balance, experience teaches that there is a difference of kind between heat and work This experience is summarized by the following facts Work is readily transformed into other forms of energy: for example, into potential energy by elevation of a weight, into kinetic energy by acceleration of a mass, into electrical energy by operation of a generator These processes can be made to approach a conversion efficiency of 100% by elimination of friction, a dissipative process that transforms work into heat Indeed, work is readily transformed completely into heat, as demonstrated by Joule's experiments On the other hand, all efforts to devise a process for the continuous conversion of heat completely into work or into mechanical or electrical energy have failed Regardless of improvements to the devices employed, conversion efficiencies do not exceed about 40% Evidently, heat is a form of energy intrinsically less useful and hence less valuable than an equal quantity of work or mechanical or electrical energy Drawing further on our experience, we know that the flow of heat between two bodies always takes place from the hotter to the cooler body, and never in the reverse direction This fact is of such significance that its restatement serves as an acceptable expression of the second law.

The observations just described suggest a general restriction on processes beyond that imposed by the first law The second law is equally well expressed in two statements that describe this restriction:

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Although this code does not inherit from BaseCodeForm as other record editors do, it still has many of the features of those forms, including a SaveFormData routine that writes records to the database. One interesting thing that this form does have is support for reading bar codes. Many bar code readers act as a wedge, inserting the text of a scanned bar code into the keyboard input stream of the computer. Any program monitoring for bar codes simply has to monitor normal text input. Bar code wedge scanners append a carriage return (the Enter key) to the end of the transmitted bar code. This lets a program detect the end of the bar code number. But in most of the Library program s forms, the Enter key triggers the OK button and closes the form. We don t want that to happen here. To prevent this, we ll add some code to this form that disables the auto-click on the OK button whenever the insertion point is in the Barcode text entry field.

FIGURE 15-3

52 Heat Engines Statement 1: No apparatus can operate in such a way that its only effect (in system and surroundings) is to convert heat absorbed by a system completely into work done by the system Statement 2: No process is possible which consists solely in the transfer of heat from one temperature level to a higher one

Statement 1 does not say that heat cannot be converted into work; only that the process cannot leave both the system and its surroundings unchanged Consider a system consisting of an ideal gas in a pistodcylinder assembly expanding reversibly at constant temperature According to Eq (23), AUt = Q W For an ideal gas, AU" 0, and therefore, Q = - W The heat absorbed by the gas from the surroundings is equal to the work transferred to the surroundings by the reversible expansion of the gas At first this might seem a contradiction of statement 1, since in the surroundings the result is the complete conversion of heat into work However, this statement requires in addition that no change occur in the system, a requirement that is not met This process is limited in another way, because the pressure of the gas soon reaches that of the surroundings, and expansion ceases Therefore, the continuous production of work from heat by this method is impossible If the original state of the system is restored in order to comply with the requirements of statement 1, energy from the surroundings in the form of work is needed to compress the gas back to its original pressure At the same time energy as heat is transferred to the surroundings to maintain constant temperature This reverse process requires at least the amount of work gained from the expansion; hence no net work is produced Evidently, statement 1 may be expressed in an alternative way, viz:

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