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Many chemical reactions start as soon as the reactants are brought together and continue until one or both reactants are used up Other reactions require energy input for the reaction to occur Reactions with large equilibrium constants are product-favored (or spontaneous) reactions Reactions with small equilibrium constants are called reactant-favored (or nonspontaneous) reactions It has been observed that reactions that lead to dispersal of energy tend to be product favored Energy can also be dispersed if the volume of a system increases This is especially true for gases There are two main factors that control the dispersal of energy: An exothermic reaction transfers heat to the surroundings, thus dispersing energy over a wider number of particles Most product-favored reactions are exothermic Some endothermic processes are product favored In these reactions spreading out of matter increases disorder This increase in disorder is measured by a quantity called entropy, S Certain qualitative generalizations can be made about entropy: S(solid) < S(liquid) << S(gas) Gases often dominate entropy because the volumes of gases are about 1000 times greater than those of solids and liquids Reactions that increase the number of gas molecules have large entropy changes The following have large positive entropy changes: H2O(l) N2O4(g) 2NH3(g) H2O(g) 2NO2(g) 3H2(g) + N2(g)

Which version(s) include Aero Which version(s) include the Windows Media Center Which version(s) include BitLocker Drive Encryption

NOTE The Windows Vista Upgrade Advisor requires connectivity to the Internet If you don t have connectivity, it will end with an error saying that either the Web service was busy or you are disconnected from the Internet 10 When the Vista Upgrade Advisor completes, click the See Details button 11 The Details report will appear as shown in Figure 1-13 This report makes a recommendation on which version appears to be the best edition for you and also lists potential issues

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12 Scroll down to the System Requirements area Note that issues are listed in the areas of System Requirements, Devices, and Programs Click any of these buttons 13 The Vista Upgrade Advisor report will appear, as shown in Figure 1-14 On my system, I have less than 13GB of free space on the C: drive, so it s informing me I need at least 15GB of disk space On your system, you may see something different 14 Scroll through the report details on the System tab to review the information 15 Select the Devices tab and scroll through the report

16 Select the Programs tab and scroll through the report 17 Select the Task List tab and scroll through the report Notice how the task list informs you specifically what you need to do before and after the installation 18 Click the Save report icon to save the report

The actual upgrade procedure is rather straightforward With one of the supported operating systems (such as Windows XP) booted, place the installation DVD into the DVD drive If Autoplay isn t enabled, browse to the DVD with Windows Explorer and doubleclick the Setup file You ll see the upgrade window appear as shown in Figure 1-15 Several links are available from this window:

Check Compatibility Online Clicking this link will take you to the Web site that allows you to download the Windows Vista Upgrade Advisor described earlier in this section Install Now Clicking this link will launch the Installation Wizard

For solid and liquid solutes, the entropy of the pure substance is less than the entropy of the mixture: S(solute) + S(solvent) < S(solution) For gaseous solutes dissolving in a liquid solvent, the opposite is true, because the volume is greatly decreased S(solute) + S(solvent) > S(solution) In general, the entropy of mixtures is greater than the entropy of pure substances The more complicated a molecule is, the greater the entropy, because there are many more possible arrangements of the molecule Each substance has an entropy of formation, So , similar to an enthalpy of formation f Ho Because the entropy of a perfect crystal of a substance at 0 K is de ned as zero, even f elements have entropies of formation values at temperatures greater than 0 K Mathematically, the equation for the entropy of a reaction is analogous to that for Ho : rxn So = n p So (products) n rSo (reactants) rxn f f

What to Know Before Installing Windows This link opens a Help And Support window that provides detailed installation instructions Transfer Files and Settings From Another Computer Clicking this link will launch the Windows Easy Transfer Wizard This tool was presented earlier in this chapter

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